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In page Timeline of thermodynamics:
"
- 1874 – Thomson formally states the second law of thermodynamics
- 1876 – Josiah Willard Gibbs publishes the first of two papers (the second appears in 1878) which discuss phase equilibria, statistical ensembles, the free energy as the driving force behind chemical reactions, and chemical thermodynamics in general.[citation needed]
- 1876 – Loschmidt criticises Boltzmann's H theorem as being incompatible with microscopic reversibility (Loschmidt's paradox).
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