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In page Photoelectric effect:

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In 1887, Heinrich Hertz observed the photoelectric effect[5] and reported on the production and reception[6] of electromagnetic waves.[7] The receiver in his apparatus consisted of a coil with a spark gap, where a spark would be seen upon detection of electromagnetic waves. He placed the apparatus in a darkened box to see the spark better. However, he noticed that the maximum spark length was reduced when inside the box. A glass panel placed between the source of electromagnetic waves and the receiver absorbed ultraviolet radiation that assisted the electrons in jumping across the gap. When removed, the spark length would increase. He observed no decrease in spark length when he replaced the glass with quartz, as quartz does not absorb UV radiation.[citation needed]