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In page Atmospheric entry:

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A radiatively cooled TPS for an entry vehicle is often called a hot-metal TPS. Early TPS designs for the Space Shuttle called for a hot-metal TPS based upon a nickel superalloy (dubbed René 41) and titanium shingles.[3] This Shuttle TPS concept was rejected, because it was believed a silica tile-based TPS would involve lower development and manufacturing costs.[citation needed] A nickel superalloy-shingle TPS was again proposed for the unsuccessful X-33 single-stage-to-orbit (SSTO) prototype.[4]