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In page Molecular orbital:

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The highest occupied molecular orbital and lowest unoccupied molecular orbital are often referred to as the HOMO and LUMO, respectively. The difference of the energies of the HOMO and LUMO is called the HOMO-LUMO gap. This notion is often the matter of confusion in literature and should be considered with caution. Its value is usually located between the fundamental gap (difference between ionization potential and electron affinity) and the optical gap. In addition, HOMO-LUMO gap can be related to a bulk material band gap or transport gap, which is usually much smaller than fundamental gap.[citation needed]