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In page Titan (rocket family):

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Liquid oxygen is dangerous to use in an enclosed space, such as a missile silo, and cannot be stored for long periods in the booster oxidizer tank. Several Atlas and Titan I rockets exploded and destroyed their silos, although without loss of life.[citation needed] The Martin Company was able to improve the design with the Titan II. The RP-1/LOX combination was replaced by a room-temperature fuel whose oxidizer did not require cryogenic storage. The same first-stage rocket engine was used with some modifications. The diameter of the second stage was increased to match the first stage. The Titan II's hypergolic fuel and oxidizer ignited on contact, but they were highly toxic and corrosive liquids. The fuel was Aerozine 50, a 50/50 mix of hydrazine and UDMH, and the oxidizer was NTO.